The show explores the worlds of its protagonists Priya Sharma (Sakshi Tanwar) and Ram Kapoor (Ram Kapoor), who accidentally discover love after they get married. Ram Kapoor is a well-reputed, rich and powerful businessman in his early 40s while Priya Sharma is in her late 30s and comes from a middle-class family. She is shown as being more sensible, philosophical and more mature than Ram.
The story begins when Ram's stepsister Natasha (Sumona Chakravarti) and Priya's younger brother Kartik (Mohit Malhotra) fall in love with each other. They want to get married, however, Kartik thinks he should not get married before his older sister. For the sake of his stepsister, Ram agrees to marry Priya to solve this problem. Initially, Ram and Priya dislike each other but as time passes and they spend more time with each other, they begin to fall in love and respect each other. However, their relationship remains difficult since every time Priya and Ram grow closer, problems arise which drive them apart. As the story progresses, several antagonists are introduced and the narrative moves between discontinuous time periods. However, finally Ram and Priya's love wins and they succeed in removing all hurdles from their life, allowing them to live happily ever after.